%appdata%\Microsoft\Excel\XLSTART is a directory where Excel searches for workbook templates and the Personal.xlsb. .xltx, .xltm) Book.xlt* and Sheet.xlt* are used as defaults when a new Excel workbook or worksheet is created. %appdata%\Microsoft\Excel\XLSTART. application.startupPath in the immediate window. C:\Program Files\Microsoft Office\root\OfficeX\XLSTART. AltStartup value under the registry key HKEY_CURRENT_USER\Software\Microsoft\Office\_version_\Excel\Options.